Saturday, February 25, 2023

What's Polluting Delhi's Air?

Air pollution in India is an issue, and city of Delhi (its capital) is one of the most studied city with a disproportionate share of media attention as compared to other cities within India. Yet, we do not seem to have decisive answers to potentially straightforward questions such as, how polluted is the city, what are the main sources, and where to start to control pollution in the city. This is an attempt to put things into perspective with a series of opinion pieces on these questions, on what Delhi (and its satellite cities) really need to improve and really need to know, so that they can clear the tag of “the most polluted city in the world” or keep it.

 An earlier post in the series focused on a “call for open air pollution data” in Delhi and other Indian cities. This is the second in the series – what are the sources of air pollution in Delhi? This is the most commonly asked question and also the most confusing and unanswered question.

 Before we start pointing fingers at various sources and laying down numbers, there are some basics that everybody needs to understand. I will try my best to make it as non-scientific as possible. Then, we will jump into the blame games.

First – there are many pollutants

Critical ones are particulate matter, nitrogen oxides, sulfur dioxide, carbon monoxide, and ozone. We should never discuss them all at once, because all are very different in their chemical nature and different in the ways they might affect our health. Most importantly, never mix air pollutants with the greenhouse gases like carbon dioxide and try to link up air quality and climate change in the same sentence. Only thing they have in common is that all of them originate from the same sources – anything burnt will produce at least one of these pollutants or all of them. How much of each of these pollutants is produced is also different, meaning a source attribution based on nitrogen oxides is not same as a source attribution based on particulate matter or carbon dioxide.

So, of these, if we have to pick one pollutant that is super critical for us, then it is particulate matter (PM). Some generally refer to this as dust, aerosols, and soot.

The PM size under 2.5 micron meter diameter is the most known harmful and measurable fraction, referred to as PM2.5. Its chemical composition has contributions from all the other gaseous components, such as, sulfur dioxide shows up as sulfate aerosols, nitrogen oxides show up as nitrate aerosols, volatile organic compounds after undergoing a series of chemical reactions with ozone, nitrogen oxides, and carbon monoxide to show up as secondary organic aerosols.

In simple language, focusing our efforts on PM2.5 to identify urban pollution sources will be enough, without mixing messages by discussing everything under the sun.

Second – PM10 and PM2.5 are different

PM10 is particulate matter under 10 micron meter diameter; PM2.5 is particulate matter under 2.5 micron meter diameter.

PM2.5 is a subset of PM10 and the ratio varies from city to city and source to source.

PM10 was, for the longest time, the only size fraction measured in India. PM2.5 was added to the list of criteria pollutants in 2009, and now measured in 20+ Indian cities using continuous monitoring stations.

Most of the PM2.5 pollution is combustion based. For example, most of the PM pollution from diesel, petrol, and CNG combustion falls under PM2.5; most of the open waste burning pollution, biomass burning pollution, and coal combustion at boilers, falls under PM2.5.

A good fraction of PM10 comes from mechanical processes – like dust resuspension. Close to 80% of the dust (that we commonly find on the roads) falls into the size fraction between PM2.5 and PM10. This is the reason for more dust in the measured PM10 samples and little dust in the measured PM2.5 samples.

Third – emission inventory is not pollution source attribution

Emissions is what comes out of the vehicle tail pipes, chimneys at the huts, industries, and power plants, trash burning, and the resuspension of dust on the roads. This is commonly measured and reported as grams of pollutant emitted per km of vehicle travel, grams of pollutant emitted per a kilo of fuel burnt, or sometimes grams of pollutant emitted per hour.

Pollution on the other hand is what we breathe and it is measured and reported as mirco-gm/m3. After the pollutants are free of their source, in other words, all the emissions are in the atmosphere, they get mixed, moved, and mangled, and end up as pollution. The net pollution that we measure at the monitoring stations can be due to all local emissions or sometimes every bit of the pollution could be a non-local emission source (examples to follow).

Fourth – diffused vs. point and local vs. non-local sources

urban air pollutionThe ground level sources like vehicle exhaust, road re-suspended dust, open waste burning, residential cooking and heating, commonly referred to as diffused sources, tend to influence the immediate vicinity and then they diffuse and disperse to the neighborhoods.

The others like industries and big power plants with stacks, their emissions have the tendency to move farther distances (depending on the local meteorological conditions) and end up as pollution not only where they are sourced, but also away.

So, in numbers, if we are looking at an emissions inventory for a city; it is possible the city may have only the diffused sources in its administrative boundary. For example, in case of Delhi, all the coal-fired thermal power plants are outside Delhi (within 20-30 km), all the brick kilns are outside Delhi, a majority of the industries are outside Delhi, which means when an emissions inventory is put together by drawing up an administrative boundary for a city, we are missing out on what we eventually breathing. Another example, come November every year, we point fingers to Punjab and Haryana, because of the crop residue burning. Is this part of the emissions inventory for Delhi – NO. However, it is part of the pollution that we are breathing, because of long range transport.

Fifth – working domain size

What is the area being covered for the emissions inventory calculations? This varies with the group conducting the study; and accordingly the results. Often this is the administrative boundary, because the city authorities like it that way. So, it is not fair to compare the emission inventory studies under the same lens, unless, the studies are for the same working domain.

It is our opinion an area of 80 km x 80 km with the Delhi metropolitan authority in the center, is a good working domain, which will cover all the known sources of pollution, which have the potential to influence the air quality in Delhi - power plants, brick kilns, and industries, besides the usual suspects - vehicle exhaust, road dust, cooking and heating, open waste burning, and diesel generator sets.

On the other hand, ambient sampling based pollution attribution doesn’t have this restriction, because the analysis starts with what is in the atmosphere (sampling), followed by the analysis of the samples for chemical markers, and statistically matched to the sources for attribution.

Sixth – city is not just roads

If all the measurements and modeling work was conducted around roads, then yes, all the pollution measured and modeled will be from vehicle exhaust and road dust. However, we have to keep in mind that roads are only part of the urban infrastructure and there are hundreds of other activities, simultaneously underway, besides vehicles on the road. For Delhi, roads account for less 20% of the urban land, with the rest covered with residential, industrial, natural, and recreational activities.

what are we looking for? 

If the goal is to find out what is polluting Delhi, then stop looking at the emission inventories and start looking at the pollution based source attribution.

The emission inventories give you an idea of the sources. If the mix of sources is not that diverse, it is possible that the attributions we find in the emissions will be similar to those we find in the ambient pollution. However, in case Delhi, this is not possible. The mix of sources in Delhi and its satellite cities is very diverse and the city is located such that the influence of the long range transport is often and large.
particulate source apportionment
How do we conduct pollution based source attribution?

Ideally, a large number of ambient samples should be collected from across the city, analysed for chemical profiles, and then statistically matched with a set of source profiles (knowing which sources are likely to influence the ambient pollution), to establish the source shares. This is what we refer to as top-down source apportionment. This is an expensive route (from sampling to analysis), but also the most accurate route. (download an illustrated note on how to conduct source apportionment)

Second method is based on emission inventory, in its full spatial and temporal gridded form, for a representative urban airshed, processed through a dispersion model on top of a 3-dimensional meteorological field. With a series of such simulations, one can establish pollution based source attributions. This is what we refer to as bottom-up source apportionment. Except for the computational needs, this is relatively less expensive, with one main constraint – the emissions inventory must cover the influential urban airshed and account for long range transport (especially in case of Delhi).

Both the methodologies are important and needed, as they compliment each other, and drive us to understand the true shares of various sources. For example, diesel burnt in the trucks, cars, buses, and generator sets will produce very similar chemical profile, which will be hard to distinguish if there is no bottom-up understanding. Similarly, biomass burnt in the fields and in the cookstoves will produce very similar chemical profile, which will be hard to distinguish if there is no bottom-up understanding.

In India, since 2000, we counted 60 top-down source apportionment studies, of which 70% are from 7 cities (Delhi, Chennai, Kolkata, Kanpur, Hyderabad, Raipur, and Mumbai) and Delhi takes the top spot with 20% of the overall studies. We summarized these in a journal article looking at the nature of air pollution in Indian cities.

what do we know? 

Based on ambient sampling and dispersion modelling, we can summarize the source attributions as below. Irrespective of all the confusion in the media (primarily stemming from combining emissions and pollution studies) studies conclude similar source shares, which make sense. For details on the study listed below, follow the links to access the full report/papers or send an email to the study contact person for more details. We are only summarizing the final results from each of the studies, as presented in the reports.

Study (1) CPCB 2010

This was a multi-city study conducted for both PM2.5 and PM10 samples, which were collected in year 2006-07. While the results from the PM2.5 samples were are not admissible (which blamed domestic LPG burning as a key urban pollution source), the results from PM10 samples made sense. We took the liberty of converting the PM10 shares into PM2.5 - assuming 15% of the dust in PM10 surviving in the PM2.5 fraction and 100% of all the other combustion sources surviving in the PM2.5 fraction. The pie graph below is an average of all samples reported in the CPCB (2010) study report.


Study (2) IIT-Kanpur (2015)

IIT Kanpur also conducted the CPCB (2010) study for Delhi and this 2015 study updated the analysis with new sample collection at six locations and two seasons (summer and winter), directly aimed at understanding the source contributions to PM2.5 pollution in Delhi. Contact person for the study details is Dr. Mukesh Sharma.

The source categories listed in this study were different from the study (1). So, we took the liberty of clubbing them for simplicity. For example, the secondary sulfate aerosols, from the chemical conversion of SO2 emissions, are likely to originate from coal and diesel consumption. Similarly, nitrate aerosols, from the chemical conversion of NOx emissions, are likely to originate from coal, diesel, and petrol combustion. Clubbed all the construction, soil, and road dust into one dust category.

Since, the categories are listed along the fuel lines, we can interpret that all the diesel and petrol is linked to the vehicle exhaust and diesel generator sets; biomass burning can be linked to the crop residue burning (especially for the winter months) and biomass used for cooking and heating; coal could be consumed at industries, cooking, and heating.

Study (3) Georgia-Tech (2007)

This is an older study conducted in four Indian cities for four seasons (see the original pie graphs). Contact person for the study details is Dr. Zohir Chowdhury. Download the study report published in the Journal of Geophysical Research and a summary report by the World Bank.

For simplicity, we clubbed the fuel categories to match the study (1) and (2) pies and averaged all the results to represent annual shares. Since, the categories are listed along the fuel lines, we can interpret that all the diesel and petrol is linked to the vehicle exhaust and diesel generator sets; biomass burning can be linked to the crop residue burning (especially for the winter months) and biomass used for cooking and heating; coal could be consumed at industries, cooking, and heating.

Study (4) UEinfo (2013)

The pie graph is an annual average based on emissions inventory and dispersion modelling, conducted at 1 km resolution for a working domain of 80 km x 80 km, including local sources like vehicle exhaust, dust resuspension, cooking and heating, power plants, industries, brick kilns, open waste burning, and diesel generator sets, and contributions from outside the modeling domain (dust storms, open biomass fires, and fossil fuel burning in the immediate vicinity of the modeling domain). Multiple dispersion model simulations were conducted to ascertain these shares by month and season. Details of the emissions inventory (spatially and temporally segregated) and modeled source apportionment are published as two journal articles – Atmospheric Environment and Environmental Development.

 An updated inventory is currently in use to model air quality forecasts over the National Capital Region; including particulate source apportionment on an hourly basis.

can we quantify pollution sources in Delhi? 

This is not an easy question to answer, but the fact remains that we have an idea based on these ambient sampling and dispersion modelling based studies, and all of them point to a certain range. On average, across the whole city
  • Vehicle exhaust is responsible for PM2.5 pollution up to 30%
  • Biomass burning (including seasonal open fires, cooking, and heating) is responsible for PM2.5 pollution up to 20%
  • Industries is responsible for PM2.5 pollution up to 20%
  • Soil and road dust is responsible for PM2.5 pollution up to 15%
  • Open waste burning is responsible for PM2.5 pollution up to 15%
  • Diesel generators is responsible for PM2.5 pollution up to 10%
  • Power plants is responsible for PM2.5 pollution up to 5%
(sum is not 100% - this is an upper estimate for all the sources)


1 comment:

Unknown said...

"Delhi turns into a Gas Chamber, Delhite Forced to Breathe Smog - Newsondot